Supramolecular structures are generated from manganese thiodiacetate (tda) units and substituted bipyridine (bipy) ligands. Analysis of the ?-stacking and DFT calculations for isolated binuclear units suggest that, in some cases, the geometry of the building blocks depends ultimately on the strength of noncovalent interactions between the 1D coordination polymers.
Supramolecular interactions as determinant factors of the geometry of metallic building blocks: tetracarboxylate dimanganese species
Mealli Carlo;Ienco Andrea;
2005
Abstract
Supramolecular structures are generated from manganese thiodiacetate (tda) units and substituted bipyridine (bipy) ligands. Analysis of the ?-stacking and DFT calculations for isolated binuclear units suggest that, in some cases, the geometry of the building blocks depends ultimately on the strength of noncovalent interactions between the 1D coordination polymers.File in questo prodotto:
Non ci sono file associati a questo prodotto.
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
