The hydrogenation of thiophenes, leading to cyclic thioethers, thiols or hydrocarbons and H2S, can be achieved by single-site metal catalysts in both homogeneous and heterogeneous phase. An overview of the processes that have provided useful mechanistic information on hydrodesulfurization catalysis, is presented and commented.
Role of single-site catalysts in the hydrogenation of thiophenes: from models systems to effective HDS catalysts
Bianchini C;Meli A;Vizza F
2004
Abstract
The hydrogenation of thiophenes, leading to cyclic thioethers, thiols or hydrocarbons and H2S, can be achieved by single-site metal catalysts in both homogeneous and heterogeneous phase. An overview of the processes that have provided useful mechanistic information on hydrodesulfurization catalysis, is presented and commented.File in questo prodotto:
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