Several carbanionic leaving groups can be easily displaced from the sulfinyl group by organometallic reagents. The reaction follows a highly stereoselective course of inversion of configuration. Provided that a ready route to the precursor sulfinyl compound is available (e.g. an enantioselective ox-idation of the corresponding sulfide), the process can be transformed into an easy and versatile procedure for the ster-eoselective synthesis of sulfoxides.
Enantioselective Routes to Sulfoxides Based Upon the Use of Carbanionic Leaving Groups
Cardellicchio C;
2004
Abstract
Several carbanionic leaving groups can be easily displaced from the sulfinyl group by organometallic reagents. The reaction follows a highly stereoselective course of inversion of configuration. Provided that a ready route to the precursor sulfinyl compound is available (e.g. an enantioselective ox-idation of the corresponding sulfide), the process can be transformed into an easy and versatile procedure for the ster-eoselective synthesis of sulfoxides.File in questo prodotto:
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