On actiVation by MAO the CoII pyridinimine dichloride complex CoCl2N2Ph catalyzes the unprecedented enchainment of one norbornene molecule with two ethylene molecules to giVe exo-2,exo-3 ethyl-Vinylnorbornane with high actiVity and complete diastereoselectivity.
Diastereoselective Alkyl-Vinylation of Norbornene Catalyzed by a Tetrahedral Pyridinimine Cobalt(II) Complex
Claudio Bianchini;Giuliano Giambastiani;Andrea Meli;
2007
Abstract
On actiVation by MAO the CoII pyridinimine dichloride complex CoCl2N2Ph catalyzes the unprecedented enchainment of one norbornene molecule with two ethylene molecules to giVe exo-2,exo-3 ethyl-Vinylnorbornane with high actiVity and complete diastereoselectivity.File in questo prodotto:
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