The potassium salt of the triphenylphosphine oxide adduct of bis(tetrachlorocatecholate)mangnnese(III) complex reacts with O-2 in the presence of K+-sequestering agents at room temperature in MeCN resulting in the formation of the corresponding Mn-IV-tris( catecholate) species.
Counter cation-controlled air oxidation of manganese derivatives of tetrachlorocatechol
Sangregorio C;
2000
Abstract
The potassium salt of the triphenylphosphine oxide adduct of bis(tetrachlorocatecholate)mangnnese(III) complex reacts with O-2 in the presence of K+-sequestering agents at room temperature in MeCN resulting in the formation of the corresponding Mn-IV-tris( catecholate) species.File in questo prodotto:
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