One-bond C-H coupling constants of the anionic carbon of anions derived from disulphones (1)-(3) provide unequivocal evidence for the trigonal hybridization of the charged carbon, previously assigned as tetrahedral; it is shown that the 1,3-dithiolane 1,1,3,3-tetraoxide undergoes ring opening upon treatment with strong bases.
TRIGONAL CONFIGURATION OF DISULFONYL CARBANIONS
FERRACCIOLI R;
1986
Abstract
One-bond C-H coupling constants of the anionic carbon of anions derived from disulphones (1)-(3) provide unequivocal evidence for the trigonal hybridization of the charged carbon, previously assigned as tetrahedral; it is shown that the 1,3-dithiolane 1,1,3,3-tetraoxide undergoes ring opening upon treatment with strong bases.File in questo prodotto:
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