The complex [CrCl3(THF)3] reacts with Li(CH2CH2CH2NMe2) in THF at room temperature (r.t.) to form the tetranuclear complex [Cr4(CH2CH2CH2NMe2)4(?4-O)(?-Cl)6] (1) where each chromium atom has a distorted octahedral coordination geometry with an oxygen atom shared among the four metal ions.

Synthesis and molecular structure of the tetranuclear mu(4)-oxo-centered chromium complex [Cr-4(CH2CH2CH2NMe2)(4)(mu(4)-O)(mu-Cl)(6)]

Ossola F;Benetollo F
1999

Abstract

The complex [CrCl3(THF)3] reacts with Li(CH2CH2CH2NMe2) in THF at room temperature (r.t.) to form the tetranuclear complex [Cr4(CH2CH2CH2NMe2)4(?4-O)(?-Cl)6] (1) where each chromium atom has a distorted octahedral coordination geometry with an oxygen atom shared among the four metal ions.
1999
CHIMICA INORGANICA E DELLE SUPERFICI
Istituto di Chimica della Materia Condensata e di Tecnologie per l'Energia - ICMATE
tetrachromium complexes
syn
crystal structure
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.14243/178633
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