A high-pressure job: Under high-pressure conditions, within a diamond anvil cell, irradiation of red phosphorus (see scheme, orange) and water was found to lead to a reaction that gives H2, PH3, H3PO2, H3PO4, and H3PO4 (H gray, O red, P orange). This reaction can be easily monitored using Raman spectroscopy and presents an interesting method for H2 generation.
High-Pressure Chemistry of Red Phosphorus and Water under Near-UV Irradiation
Ceppatelli, Matteo;Bini, Roberto;Caporali, Maria;Peruzzini, Maurizio
2013
Abstract
A high-pressure job: Under high-pressure conditions, within a diamond anvil cell, irradiation of red phosphorus (see scheme, orange) and water was found to lead to a reaction that gives H2, PH3, H3PO2, H3PO4, and H3PO4 (H gray, O red, P orange). This reaction can be easily monitored using Raman spectroscopy and presents an interesting method for H2 generation.File in questo prodotto:
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Descrizione: High-Pressure Chemistry of Red Phosphorus and Water under Near-UV Irradiation
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