We report on the high pressure synthesis of BiMn7O12, a manganite displaying a "quadruple perovskite" structure. Structural characterization of single crystal samples shows a distorted and asymmetrical coordination around the Bi atom, due to presence of the 6s 2 lone pair, resulting in non-centrosymmetric space group Im, leading to a permanent electrical dipole moment and ferroelectric properties. On the other hand, magnetic characterization reveals antiferromagnetic transitions, in agreement with the isostructural compounds, thus evidencing two intrinsic properties that make BiMn7O12 a promising multiferroic material.
Synthesis and characterization of multiferroic BiMn7O12
F Mezzadri;M Calicchio;E Gilioli;F Bolzoni;R Cabassi;
2008
Abstract
We report on the high pressure synthesis of BiMn7O12, a manganite displaying a "quadruple perovskite" structure. Structural characterization of single crystal samples shows a distorted and asymmetrical coordination around the Bi atom, due to presence of the 6s 2 lone pair, resulting in non-centrosymmetric space group Im, leading to a permanent electrical dipole moment and ferroelectric properties. On the other hand, magnetic characterization reveals antiferromagnetic transitions, in agreement with the isostructural compounds, thus evidencing two intrinsic properties that make BiMn7O12 a promising multiferroic material.File in questo prodotto:
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