Copper-organodiamine substructures are effective bridging groups for polyoxomolybdate anions in the construction of two-dimensional mixed metal networks, of which [{Cu(bpe)}(4)(alpha-Mo8O26)]. 2H(2)O and [{Cu(pyrd)}(4)(gamma-H4Mo8O26)] are representative [bpe = 1,2-bis(4-pyridyl)ethylene; pyrd = pyridazine].
Solid state coordination chemistry: two-dimensional oxides constructed from polyoxomolybdate clusters and copper-organoamine subunits
Sangregorio C;
1998
Abstract
Copper-organodiamine substructures are effective bridging groups for polyoxomolybdate anions in the construction of two-dimensional mixed metal networks, of which [{Cu(bpe)}(4)(alpha-Mo8O26)]. 2H(2)O and [{Cu(pyrd)}(4)(gamma-H4Mo8O26)] are representative [bpe = 1,2-bis(4-pyridyl)ethylene; pyrd = pyridazine].File in questo prodotto:
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