An analysis of the dynamics is performed of exactly solvable models for fragile and strong glasses, exploiting the partitioning of the free-energy landscape in inherent structures. The results are compared with the exact solution of the dynamics, by employing the formulation of an effective temperature used in literature. Also, a statistical mechanics formulation is introduced, based upon general statistical considerations, which performs better. Though the considered models are conceptually simple, there is no limit in which the dynamics may be exactly described by a symbolic dynamics of the system moving through consistently weighted inherent structures.

Inherent structures in models for fragile and strong glass

Leuzzi L;
2001

Abstract

An analysis of the dynamics is performed of exactly solvable models for fragile and strong glasses, exploiting the partitioning of the free-energy landscape in inherent structures. The results are compared with the exact solution of the dynamics, by employing the formulation of an effective temperature used in literature. Also, a statistical mechanics formulation is introduced, based upon general statistical considerations, which performs better. Though the considered models are conceptually simple, there is no limit in which the dynamics may be exactly described by a symbolic dynamics of the system moving through consistently weighted inherent structures.
2001
Istituto per i Processi Chimico-Fisici - IPCF
SPIN-GLASS; SUPERCOOLED LIQUIDS; ENERGY LANDSCAPE; PHASE TRANSITION; GLASSY STATE
File in questo prodotto:
File Dimensione Formato  
prod_254682-doc_68792.pdf

solo utenti autorizzati

Descrizione: Inherent structures in models for fragile and strong glass
Dimensione 305.23 kB
Formato Adobe PDF
305.23 kB Adobe PDF   Visualizza/Apri   Richiedi una copia

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.14243/197749
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 0
  • ???jsp.display-item.citation.isi??? 12
social impact