Functionalized oxiranyl ethers can be regio- and stereoselectively converted into hydroxy oxetanes or cis-diols by treatment with organometallic bases. These two rearrangements can be conveniently carried out either using different reaction conditions starting from the oxirane or in two consecutive steps from the oxirane via the oxetane
Useful base promoted elaborations of oxiranyl ethers
Mordini Alessandro;Reginato Gianna;
2001
Abstract
Functionalized oxiranyl ethers can be regio- and stereoselectively converted into hydroxy oxetanes or cis-diols by treatment with organometallic bases. These two rearrangements can be conveniently carried out either using different reaction conditions starting from the oxirane or in two consecutive steps from the oxirane via the oxetaneFile in questo prodotto:
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