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Reaction of several ?-silyl acetylenic ketones with hexamethyldisilathiane (HMDST) in the presence of TfOTMS affords a simple and direct entry to silylated acetylenic thioketones and, after desilylation, to the corresponding unsubstituted ?,?-unsaturated thioketones. The procedure similarly affords the first synthesis of an acetylenic thioaldehyde

The first synthesis of alpha-beta acetylenic thioketones and thioaldehydes

Mordini Alessandro;Reginato Gianna
1999

Abstract

Reaction of several ?-silyl acetylenic ketones with hexamethyldisilathiane (HMDST) in the presence of TfOTMS affords a simple and direct entry to silylated acetylenic thioketones and, after desilylation, to the corresponding unsubstituted ?,?-unsaturated thioketones. The procedure similarly affords the first synthesis of an acetylenic thioaldehyde
1999
Inglese
SYNLETT
1739
Sì, ma tipo non specificato
alkynes - cycloadditions - silicon - thionation - thiocarbonyl
2
info:eu-repo/semantics/article
262
Capperucci, Atonella; Degl'Innocenti, Alessandro; Scafato, Patrizia; Mecca, Tommaso; Mordini, Alessandro; Reginato, Gianna
01 Contributo su Rivista::01.01 Articolo in rivista
none
01.01 Articolo in rivista
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.14243/199068
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