Silyl enol ethers 1 react under the influence of diethyl ether-boron trifluoride complex with silylated sulphides to afford a new and general access to a wide range of vinyl sulphides 2. When ?,?-unsaturated ketones are used, a mild synthesis of 1,3-bis(phenylthio)propenes 6 is achieved
Thiosilanes in organic synthesis: a novel approach to vinyl sulphides
Mordini Alessandro;Reginato Gianna;
1992
Abstract
Silyl enol ethers 1 react under the influence of diethyl ether-boron trifluoride complex with silylated sulphides to afford a new and general access to a wide range of vinyl sulphides 2. When ?,?-unsaturated ketones are used, a mild synthesis of 1,3-bis(phenylthio)propenes 6 is achievedFile in questo prodotto:
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