Excimer laser (248 nm, 15 ns) photoablation products from the polymers PMMA and polystyrene are directly observed using picosecond uv laser (290 nm, 1 ps) ionization time-of-flight mass spectroscopy. Species heavier than the monomer masses are detected, which cannot be attributed to simple direct fragments of the polymer chains, but rather show the importance of fast chemistry and/or photochemistry during the ablation process. © 1987 Springer-Verlag.

Direct observation of excimer-laser photoablation products from polymers by picosecond-uv-laser mass spectroscopy

Larciprete R;
1987

Abstract

Excimer laser (248 nm, 15 ns) photoablation products from the polymers PMMA and polystyrene are directly observed using picosecond uv laser (290 nm, 1 ps) ionization time-of-flight mass spectroscopy. Species heavier than the monomer masses are detected, which cannot be attributed to simple direct fragments of the polymer chains, but rather show the importance of fast chemistry and/or photochemistry during the ablation process. © 1987 Springer-Verlag.
1987
CHEMICAL REACTIONS - Photochemical Reactions
LASER BEAMS - Effects
LASERS
EXCIMER - Applications
POLYSTYRENES - Ablation
ULTRAVIOLET RADIATION
MASS SPECTROSCOPY
PHOTOABLATION PRODUCTS
POLYMETHYL METHACRYLATE
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.14243/199548
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