Ethyl (diethoxyphosphoryl)thionformate, ethyl (diethoxythiophosphoryl) thionformate. ethyl (diethoxyphosphoryl)(thiolformate, and ethyl (die thoxythiophosphorl)thiolformate have been allowed to react with a variety of in situ generated free radicals. Spin adducts were observed by EPR with the two thionesters but not with thiolesters even the former compounds, however. exhibited a remarkably lower reactivity than similarly substituted dithioesters.

Spin trapping with phosphonothionesters. Part VI. Phosphoryl- and thiophosphoryl-thionformates

A Alberti;M Benaglia;D Macciantelli;
2001-01-01

Abstract

Ethyl (diethoxyphosphoryl)thionformate, ethyl (diethoxythiophosphoryl) thionformate. ethyl (diethoxyphosphoryl)(thiolformate, and ethyl (die thoxythiophosphorl)thiolformate have been allowed to react with a variety of in situ generated free radicals. Spin adducts were observed by EPR with the two thionesters but not with thiolesters even the former compounds, however. exhibited a remarkably lower reactivity than similarly substituted dithioesters.
2001
Istituto per la Sintesi Organica e la Fotoreattivita' - ISOF
FRAGMENTATION CHAIN TRANSFER; OXYGEN-CENTERED RADICALS; TRANSFER RAFT; TERT-BUTYL; IN-VITRO; N-OXIDE; RESONANCE; POLYMERIZATION; THIOKETONES; AGENTS
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.14243/200059
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