The silylcupration of N-phenyl-N-ethynyl-aniline, occurs regioselectively leading to silylation at the ?-carbon atom. Subsequent reaction of the resulting vinyl copper adduct with electrophiles, opens a new flexible route to functionalized enamines.
Silylcupration of N-phenyl-N-ethynyl-aniline: a versatile route to functionalized N,N-bis-(phenyl)enamines
Reginato Gianna;
1993
Abstract
The silylcupration of N-phenyl-N-ethynyl-aniline, occurs regioselectively leading to silylation at the ?-carbon atom. Subsequent reaction of the resulting vinyl copper adduct with electrophiles, opens a new flexible route to functionalized enamines.File in questo prodotto:
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