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R)-(+)-Ferrocene cyanohydrin acetate, obtained by enzymatic acylation of ferrocene cyanohydrin, may be transformed by reduction and alkylation into novel ferrocenyl ?-aminoalcohoIs. Substitution of acetate by methanolic HNMe2 proceeds with racemisation, but significant diastereoselection is observed on Strecker reaction using (-)PhCH(Me)NHMe

Lipase catalysed resolution of ferrocene cyanohydrin: Access to novel ferrocenyl aminoalcohoIs and diamines

Giovanni Nicolosi;Angela Patti;
1997

Abstract

R)-(+)-Ferrocene cyanohydrin acetate, obtained by enzymatic acylation of ferrocene cyanohydrin, may be transformed by reduction and alkylation into novel ferrocenyl ?-aminoalcohoIs. Substitution of acetate by methanolic HNMe2 proceeds with racemisation, but significant diastereoselection is observed on Strecker reaction using (-)PhCH(Me)NHMe
1997
Inglese
8
1027
1030
4
http://www.sciencedirect.com/science/article/pii/S095741669700092X
Sì, ma tipo non specificato
2
info:eu-repo/semantics/article
262
James A.S. Howell; Kristina Humphries; Patrick McArdle; Desmond Cunningham; Giovanni Nicolosi; Angela Patti; Martin A. Walsh
01 Contributo su Rivista::01.01 Articolo in rivista
none
01.01 Articolo in rivista
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.14243/201492
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