The paper describes an asymmetric convergent synthesis of 2-epi-saponaceolide B, illustrating a general approach to the construction of the saponaceolide structure. The strategic C10'-C11' bond was formed by coupling a lithium salt containing the left part of the molecule with a carbonyl derivative representing the right part.
Studies on the Total Synthesis of the Saponaceolides. 2. Enantioselective Synthesis of 2-epi-Saponaceolide B.
SERRA STEFANO
1999
Abstract
The paper describes an asymmetric convergent synthesis of 2-epi-saponaceolide B, illustrating a general approach to the construction of the saponaceolide structure. The strategic C10'-C11' bond was formed by coupling a lithium salt containing the left part of the molecule with a carbonyl derivative representing the right part.File in questo prodotto:
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