The reaction of (1 -2:!5-6-q-cyclo-octa-1,5-diene) (1 -6-q-cyclo-octa-I ,3,5-triene)ruthenium with P(OMe)3 yielded the title compound which has been structurally characterized by X-ray diffraction studies. The complex crystallizes in the monoclinic space group P2, /n with unit-cell dimensions a = 13.306(5), b = 9.628(3), c = 16.382(20) A, p = 11 1.62(6)", and Z = 4. The co-ordination geometry around the ruthenium is a distorted square pyramid whose vertices are occupied by the phosphite ligand, the butadiene moiety of cyclo-octatriene, and the two double bonds of cyclo-octadiene.
The chemistry of (1-2:5-6-?-cyclo1-5octadiene)1-6-?-cycloocta1,3,5-triene)Ru(0): preparation and X-ray crystal structure of (trimethyl-phosphite) der
Porzio W;
1983
Abstract
The reaction of (1 -2:!5-6-q-cyclo-octa-1,5-diene) (1 -6-q-cyclo-octa-I ,3,5-triene)ruthenium with P(OMe)3 yielded the title compound which has been structurally characterized by X-ray diffraction studies. The complex crystallizes in the monoclinic space group P2, /n with unit-cell dimensions a = 13.306(5), b = 9.628(3), c = 16.382(20) A, p = 11 1.62(6)", and Z = 4. The co-ordination geometry around the ruthenium is a distorted square pyramid whose vertices are occupied by the phosphite ligand, the butadiene moiety of cyclo-octatriene, and the two double bonds of cyclo-octadiene.File in questo prodotto:
| File | Dimensione | Formato | |
|---|---|---|---|
|
prod_238537-doc_61198.pdf
solo utenti autorizzati
Descrizione: The chemistry of (1-2:5-6-?-cyclo1-5octadiene)1-6-?-cycloocta1,3,5-triene)Ru(0): preparation and X-ray crystal structure of (trimethyl-phosphite) der
Dimensione
374.92 kB
Formato
Adobe PDF
|
374.92 kB | Adobe PDF | Visualizza/Apri Richiedi una copia |
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
