Trans-PtH2(PCy3)2 (1) reacts with phenylisocyanate (2) and with diphenylketene (3) to yield the formamido complex (4) and the vinyloxo complex (5) respectively. The structure of 5 has been determined by X-ray diffraction.
Reactions of trans-[Pt(H2){P(C6H11)3}2] with heterocumulenes. The crystal and molecular structure of trans-[Pt{P(C6H11)3}2(H){OCH?C(C6H5)2}]
W Porzio;S Destri;
1986
Abstract
Trans-PtH2(PCy3)2 (1) reacts with phenylisocyanate (2) and with diphenylketene (3) to yield the formamido complex (4) and the vinyloxo complex (5) respectively. The structure of 5 has been determined by X-ray diffraction.File in questo prodotto:
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Descrizione: articolo:REACTIONS OF TRANS-[PT(H2)(P(C6H11)3] WITH HETEROCUMULENES - THE CRYSTAL AND MOLECULAR-STRUCTURE OF TRANS-[PT(P(C6H11)3)2(H)(OCH=C(C6H5)2)]
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