Real and imaginary dielectric spectra of pure, and sodium thiocyanate (NaSCN) salt complexed polyethylene oxide (PEO) have been measured as a function of temperature in the region of the ? relaxation peak. The results support previous assumptions; the concentration of the amorphous phase and the conductivity depend on the salt content. In this temperature range the dielectric loss is apparently the sum of a pure Gaussian ? relaxation (always present in amorphous polymers) and an additional component which linearly increases with temperature. The microscopic origin of the additional loss needs to be clarified.

Dielectric ­­­y relaxation in NaSCN salt complexed PEO

A Bartolotta;G Di Marco;
1993

Abstract

Real and imaginary dielectric spectra of pure, and sodium thiocyanate (NaSCN) salt complexed polyethylene oxide (PEO) have been measured as a function of temperature in the region of the ? relaxation peak. The results support previous assumptions; the concentration of the amorphous phase and the conductivity depend on the salt content. In this temperature range the dielectric loss is apparently the sum of a pure Gaussian ? relaxation (always present in amorphous polymers) and an additional component which linearly increases with temperature. The microscopic origin of the additional loss needs to be clarified.
1993
Istituto per i Processi Chimico-Fisici - IPCF
File in questo prodotto:
Non ci sono file associati a questo prodotto.

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.14243/207922
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus ND
  • ???jsp.display-item.citation.isi??? ND
social impact