Chiral t-Boc protected propargylic amines have been obtained starting from aminoaldehydes derived from natural aminoacids. Stannylcupration of these substrates affords an easy regio- and stereocontrolled route to the corresponding ?-stannylated (E)-allylamines which are useful intermediates for the synthesis of the corresponding ?-funtionalized allylic systems
A new stereoselective synthesis of chiral ??functionalized allylic amines
Reginato Gianna;Mordini Alessandro;
1996
Abstract
Chiral t-Boc protected propargylic amines have been obtained starting from aminoaldehydes derived from natural aminoacids. Stannylcupration of these substrates affords an easy regio- and stereocontrolled route to the corresponding ?-stannylated (E)-allylamines which are useful intermediates for the synthesis of the corresponding ?-funtionalized allylic systemsFile in questo prodotto:
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