Electron paramagnetic resonance has been used to characterise free radicals formed by the reaction of photochemically generated tert-butoxyl radicals with a range of methyl substituted cyclopentenones and cyclohexenones. The spectra have been interpreted using computer analysis and simulation and assigned to cyclic allylic and alkyl radicals formed by abstraction of a hydrogen atom. The 1-oxocyclohept-2-en-4-yl radical derived by abstraction of bromine from 4-bromocyclohept-2-enone exhibits a temperature dependent EPR spectrum attributed to ring inversion.
Free radicals from cyclic enones: an electron paramagnetic resonance investigation. Part 1. Radicals formed by hydrogen abstraction
A Alberti;M Benaglia;D Macciantelli
1997
Abstract
Electron paramagnetic resonance has been used to characterise free radicals formed by the reaction of photochemically generated tert-butoxyl radicals with a range of methyl substituted cyclopentenones and cyclohexenones. The spectra have been interpreted using computer analysis and simulation and assigned to cyclic allylic and alkyl radicals formed by abstraction of a hydrogen atom. The 1-oxocyclohept-2-en-4-yl radical derived by abstraction of bromine from 4-bromocyclohept-2-enone exhibits a temperature dependent EPR spectrum attributed to ring inversion.File in questo prodotto:
Non ci sono file associati a questo prodotto.
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
