Chloroperoxidase from Caldariomyces fumago catalyses the oxidation of prochiral 1,3-cyclohexadiene using TBHP as terminal oxidant. The process occurs enantioselectively and furnishes the non-racemic trans diols 1,2- and 1,4-dihydroxycyclohexene, (-)-3 and (+)-4, in good ee and yield.
Asymmetric oxidation of 1,3-cyclohexadiene catalysed by chloroperoxidase from Caldariomyces fumago
Sanfilippo C;Patti A;Nicolosi;
2000
Abstract
Chloroperoxidase from Caldariomyces fumago catalyses the oxidation of prochiral 1,3-cyclohexadiene using TBHP as terminal oxidant. The process occurs enantioselectively and furnishes the non-racemic trans diols 1,2- and 1,4-dihydroxycyclohexene, (-)-3 and (+)-4, in good ee and yield.File in questo prodotto:
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