A ferrocenyl amino alcohol possessing only planar chirality has been employed as a catalyst in the enantioselective alkylation of aldehydes with Et2Zn. Seven chiral secondary alcohols in 64?83% e.e. have been prepared.
Enantiopure 1-hydroxymethyl-2-dimethylaminomethylferrocene as efficient catalyst in the enantioselective addition of diethylzinc to aldehydes
Giovanni Nicolosi;Angela Patti;Raffaele Morrone;
1994
Abstract
A ferrocenyl amino alcohol possessing only planar chirality has been employed as a catalyst in the enantioselective alkylation of aldehydes with Et2Zn. Seven chiral secondary alcohols in 64?83% e.e. have been prepared.File in questo prodotto:
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