In the presence of the sodium salt of a bulky anion, which allows the solubility of Na+ in low polarity solvents, various tetra((4-pyridyl)porphyrin derivatives can spontaneously self-assemble from CH2Cl2 into supramolecular nanostructures exhibiting a long-range order, through the coordination of Na+ ions by the pyridyl moieties at the macrocycle periphery.
Metal-mediated self-assembly of tetrapyridyl porphyrins by Na+ ions
Trapani;Mariachiara;Plutino;Maria Rosaria;Anna;De Luca;Giovanna;Scolaro;Luigi Monsu
2012
Abstract
In the presence of the sodium salt of a bulky anion, which allows the solubility of Na+ in low polarity solvents, various tetra((4-pyridyl)porphyrin derivatives can spontaneously self-assemble from CH2Cl2 into supramolecular nanostructures exhibiting a long-range order, through the coordination of Na+ ions by the pyridyl moieties at the macrocycle periphery.File in questo prodotto:
Non ci sono file associati a questo prodotto.
I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
