The isomerization of alkoxy oxiranes with chiral lithium amides has been carefully investigated with the aim of finding an enantioselective approach to hydroxy enol ethers. Thus, the stereoselectivities and enantiomeric excesses for ring opening of cis- or trans-2,3-epoxy-1-methoxymethoxyoctane in presence of chiral lithium amides are reported.
Kinetic resolution of racemic alkoxy oxiranes by chiral lithium amides
Mordini Alessandro;
1998
Abstract
The isomerization of alkoxy oxiranes with chiral lithium amides has been carefully investigated with the aim of finding an enantioselective approach to hydroxy enol ethers. Thus, the stereoselectivities and enantiomeric excesses for ring opening of cis- or trans-2,3-epoxy-1-methoxymethoxyoctane in presence of chiral lithium amides are reported.File in questo prodotto:
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