Energy transfer tayloring in conjugated molecular architectures

In alpha- sexithienyl (T-6) molecular thin films the spectral features of photoluminescence can be correlated to precise structural topologies and the nature of photoluminescence can be controlled. AFM images show that the topological features of T-6 films evolve progressively from 2D to 3D structures with film thickness. It is shown that coalescence between different domains results in photoluminescence spectra that are dominated by the by the aggregate emission. The Figure shows the photoluminescence spectra of submonolayer and lamellae architectures.