In this article, a brief review of the recent functionalizations of the cage-like water soluble phosphine 1,3,5-triaza-7-phosphaadamantane (PTA), involving N-quaternization (lower rim) and introduction of a side arm in C-6 position (upper rim) will be presented, highlighting selected examples in their use as ligands for ruthenium(II), iridium(I), and rhodium(I) moieties together with applications of the related complexes in homogeneous catalysis.
Lower- and upper-rim-modified derivatives of 1,3,5-triaza-7-phosphaadamantane: Coordination chemistry and applications in catalytic reactions in water
Gonsalvi Luca
;Guerriero Antonella;Reginato Gianna;Peruzzini Maurizio
2013
Abstract
In this article, a brief review of the recent functionalizations of the cage-like water soluble phosphine 1,3,5-triaza-7-phosphaadamantane (PTA), involving N-quaternization (lower rim) and introduction of a side arm in C-6 position (upper rim) will be presented, highlighting selected examples in their use as ligands for ruthenium(II), iridium(I), and rhodium(I) moieties together with applications of the related complexes in homogeneous catalysis.File in questo prodotto:
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Descrizione: Lower- and upper-rim-modified derivatives of 1,3,5-triaza-7-phosphaadamantane
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