The selectivity of alpha-oxidation of ethers to esters via RuNaOCl can be dramatically improved by pH control, at high substrate to catalyst ratios using a stoichiometric amount of hypochlorite in biphasic media at room temperature.
Highly efficient use of NaOCl in the Ru-catalysed oxidation of aliphatic ethers to esters
Gonsalvi Luca;
2002
Abstract
The selectivity of alpha-oxidation of ethers to esters via RuNaOCl can be dramatically improved by pH control, at high substrate to catalyst ratios using a stoichiometric amount of hypochlorite in biphasic media at room temperature.File in questo prodotto:
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Descrizione: Highly efficient use of NaOCl in the Ru-catalysed oxidation of aliphatic ethers to esters
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