We report the newly developed conditions for the process intensification of the Suzuki-Miyaura reaction under flow over sol-gel entrapped SiliaCat DPP-Pd catalyst with the aim of practical applications. Considerably more concentrated solutions (0.5-1.0 M) are applied, and flow rate is increased up to the practically relevant 1.0 mL/min threshold. Results indicate complete coupling conversion of several different aryl halides and provide important information of general validity of vital importance for successful process intensification.
Process intensification of the Suzuki-Miyaura reaction over sol-gel entrapped catalyst silia cat DPP-Pd under conditions of continuous flow
Ciriminna Rosaria;Pagliaro Mario
2014
Abstract
We report the newly developed conditions for the process intensification of the Suzuki-Miyaura reaction under flow over sol-gel entrapped SiliaCat DPP-Pd catalyst with the aim of practical applications. Considerably more concentrated solutions (0.5-1.0 M) are applied, and flow rate is increased up to the practically relevant 1.0 mL/min threshold. Results indicate complete coupling conversion of several different aryl halides and provide important information of general validity of vital importance for successful process intensification.File in questo prodotto:
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