A pathway for the formation of 3-butadienyl-1-tosylpyrroles from 3-acyl derivatives via secondary and tertiary 3-hydroxyalkyl-1-tosylpyrroles has been developed. The dehydration of the alcohols intermediates is the crucial step: conditions for high chemo- and diastereocontrol are described. © 2014 HeteroCorporation.
Synthesis of 3-Butadienyl-1-tosylpyrroles
Settambolo R
2015
Abstract
A pathway for the formation of 3-butadienyl-1-tosylpyrroles from 3-acyl derivatives via secondary and tertiary 3-hydroxyalkyl-1-tosylpyrroles has been developed. The dehydration of the alcohols intermediates is the crucial step: conditions for high chemo- and diastereocontrol are described. © 2014 HeteroCorporation.File in questo prodotto:
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