The thermo-elastic behaviour and the temperature-induced structure evolution of a natural Fe-free zoisite have been investigated by in situ single-crystal X-ray and neutron diffraction. Neither discontinuities in volume expansion nor changes in symmetry have been observed up to 1,023 K. Zoisite shows a negative thermal expansion along [100] at T[700 K, while a continuous positive expansion occurs on the (100) plane. Two different regimes in the anisotropic thermal behaviour of zoisite can be distinguished (i.e. at T\700 K and T[700 K), corresponding to an increase in the volumetric thermal expansion at T[700 K. The structure evolution with temperature has been described by a series of X-ray and neutron refinements at different temperatures. In particular,the M(3) polyhedra show a significant octahedral flattening and expansion in the equatorial plane with T. All [SiO4] tetrahedra show a regularization with increasing T. The neutron refinements show no change in the configuration of the hydrogen bonding at least up to 873 K. The effects of the T-induced main deformation mechanisms on the anisotropic elastic behaviour of zoisite are discussed. A comparison with the thermal behaviour of epidote has been carried out.
Thermal expansion and high temperature structure evolution of zoisite by single-crystal X-ray and neutron diffraction
Gatta GD;
2012
Abstract
The thermo-elastic behaviour and the temperature-induced structure evolution of a natural Fe-free zoisite have been investigated by in situ single-crystal X-ray and neutron diffraction. Neither discontinuities in volume expansion nor changes in symmetry have been observed up to 1,023 K. Zoisite shows a negative thermal expansion along [100] at T[700 K, while a continuous positive expansion occurs on the (100) plane. Two different regimes in the anisotropic thermal behaviour of zoisite can be distinguished (i.e. at T\700 K and T[700 K), corresponding to an increase in the volumetric thermal expansion at T[700 K. The structure evolution with temperature has been described by a series of X-ray and neutron refinements at different temperatures. In particular,the M(3) polyhedra show a significant octahedral flattening and expansion in the equatorial plane with T. All [SiO4] tetrahedra show a regularization with increasing T. The neutron refinements show no change in the configuration of the hydrogen bonding at least up to 873 K. The effects of the T-induced main deformation mechanisms on the anisotropic elastic behaviour of zoisite are discussed. A comparison with the thermal behaviour of epidote has been carried out.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.