The intensities of the X and A valence photoelectron lines of N2 have been found to display Fano line shapes as a function of photon energy around the N 1s-> Rydberg excitations. The vibrational intensity distributions of these photoelectron lines change at the N 1s->3s? and 3p? resonances. These effects indicate interference between direct and resonant photoionization channels. Our numerical simulations reproduce quite well the experimental results.
Valence photoionization of the N2 molecule in the region of the N 1s-> Rydberg excitations
R Flammini;M Coreno;
2012
Abstract
The intensities of the X and A valence photoelectron lines of N2 have been found to display Fano line shapes as a function of photon energy around the N 1s-> Rydberg excitations. The vibrational intensity distributions of these photoelectron lines change at the N 1s->3s? and 3p? resonances. These effects indicate interference between direct and resonant photoionization channels. Our numerical simulations reproduce quite well the experimental results.File in questo prodotto:
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