Copper-mediated stereoselective cyclotrimerisation of polycyclic alkenes is reported. The mechanism involved provides strong support for the involvement of a CuIII intermediate in cross-coupling reactions of sp2-carbon atoms.

Role of Copper in the Stereoselective Metal-Promoted Cyclotrimerisation of Polycyclic Alkenes

Peluso P;
2002

Abstract

Copper-mediated stereoselective cyclotrimerisation of polycyclic alkenes is reported. The mechanism involved provides strong support for the involvement of a CuIII intermediate in cross-coupling reactions of sp2-carbon atoms.
2002
Istituto di Chimica Biomolecolare - ICB - Sede Pozzuoli
Copper
Cross-coupling
Molecular discrimination
Cyclization
Alkenes
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.14243/238621
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