High pressure chemical reactions of molecular systems are discussed considering the various factors thatcan affect the reactivity. These include steric hindrance and geometrical constraints in the confined envi-ronment of crystals at high pressure, changes of the free energy landscape with pressure, photoactivationby two-photon absorption, local and collective effects. A classification of the chemical reactions at highpressure is attempted on the basis of the prevailing factors.
From simple to complex and backwards. Chemical reactions under very high pressure
Bini Roberto;Ceppatelli Matteo;
2012
Abstract
High pressure chemical reactions of molecular systems are discussed considering the various factors thatcan affect the reactivity. These include steric hindrance and geometrical constraints in the confined envi-ronment of crystals at high pressure, changes of the free energy landscape with pressure, photoactivationby two-photon absorption, local and collective effects. A classification of the chemical reactions at highpressure is attempted on the basis of the prevailing factors.File in questo prodotto:
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Descrizione: From simple to complex and backwards. Chemical reactions under very high pressure
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