The electronic structure of FeSe1?xTex chalcogenide superconductors has been studied by x-ray emission (XES) and x-ray absorption (XAS) as a function of Te substitution. The Fe K XES spectra reveal a relatively low spin state for Fe in FeSe(1-x)Te(x) superconductors, persisting in the whole range of Te substitution. The Fe K-edge high-resolution XAS shows systematic spectral changes due to the evolving hybridization between the Fe 3d (4p) and chalcogen p (d) orbitals. The resonant inelastic x-ray scattering (RIXS) spectra hardly show any feature except the one due to charge transfer from occupied to unoccupied bands, that changes substantially from FeSe to FeTe. The results provide important information on the electronic states and their evolution in the FeSe1?xTex chalcogenides.
Electronic properties of FeSe(1-x)Te(x) probed by x-ray emission and absorption spectroscopy
G Baldi;
2012
Abstract
The electronic structure of FeSe1?xTex chalcogenide superconductors has been studied by x-ray emission (XES) and x-ray absorption (XAS) as a function of Te substitution. The Fe K XES spectra reveal a relatively low spin state for Fe in FeSe(1-x)Te(x) superconductors, persisting in the whole range of Te substitution. The Fe K-edge high-resolution XAS shows systematic spectral changes due to the evolving hybridization between the Fe 3d (4p) and chalcogen p (d) orbitals. The resonant inelastic x-ray scattering (RIXS) spectra hardly show any feature except the one due to charge transfer from occupied to unoccupied bands, that changes substantially from FeSe to FeTe. The results provide important information on the electronic states and their evolution in the FeSe1?xTex chalcogenides.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
