Sodic-ferri-ferropedrizite and ferri-clinoferroholmquistite, mineral data and degree of order of the A-site cations in Li-rich amphiboles.

A systematic examination of metamorphic episyenites in the Pedriza Massif, Sierra de Guadarrama, Spain, allowed detection of two more distinct Li-rich C2/m amphibole species. They can be related to previously described species via the homovalent exchanges M1(Fe2+Mg-1) and M2(Fe3+Al-1), and represent the compositions richest in Fe in this compositional space. The ideal formula of ferri-clinoferroholmquistite is A BLi2 C(Fe3+ 2Fe2+3) TSi8 O22 X(OH)2, and that of sodic-ferri-ferropedrizite is ANa BLi2C(Fe3+2Fe2+ 2Li) TSi8 O22 X(OH)2, with Z = 2. Holotype ferri-clinoferroholmquistite (IMA-CNMMN 2001-066), A(Na0.28K0.00)0.28B(Li1.90Na0.08Ca0.02)2.00 C(Fe3+1.68Fe2+1.55Mg1.06Li0.28Al0.26Ti0.01Mn2+ 0.14Zn0.02)5.00 TSi8.00 O22O3(OH1.79F0.24)2.03, has a 9.462(6), b 17.898(9), c 5.302(3) Å, 101.88(4)°, V 878.6(2) Å3. Holotype sodic-ferri-ferropedrizite (IMA-CNMMN 2001-068), A(Na0.53K0.03)0.56 B(Li1.82Na0.15Ca0.03)2.00 C(Fe3+1.55Fe2+1.49Mg0.95Li0.58Al0.21Ti0.13 Mn2+0.07Zn0.01)4.99 TSi8.00 O22 X(OH1.45F0.52)1.97, has a 9.496(4), b 17.883(8), c 5.297(2) Å, 102.06(3)°, V 879.6(2) Å3. Sodic-ferri-ferropedrizite and ferriclinoferroholmquistite are both black, with a vitreous luster. They have a gray streak and do not show fluorescence under longand short-wave ultraviolet light; they are brittle with an uneven fracture, and have the characteristic {110} cleavage of monoclinic amphiboles. The calculated values of density are 3.23 and 3.24 g/cm3, and the calculated mean indices of refraction are 1.708 and 1.710, respectively. The shape of the electron density at the A sites changes as a function of the BLi and CLi contents, suggesting that cation ordering is strongly affected by local bond-valence requirements. This feature is confirmed by systematic bondvalence - bond-strength calculations, which support the sequence (M4'Li-O3F-AmNa) > (M4'Li-O3OH-AmNa) of preferred local configurations.