A new approach to 2, a key intermediate of a previous synthesis of the tetracyclic diterpene diol stemarin, 1, based on the application of the Wiesner photochemical method to the 8(9)-podocarpen-14-one, 3, was verified by means of model compound studies and MM calculations.
Studies for a diastereoselective synthesis of the tetracyclic diterpenic diol stemarin. a model work for the preparation, from an 8(9)-podocarpen-14-one, of a key intermediate by the wiesner photochemical method
De Chiara G;
1996
Abstract
A new approach to 2, a key intermediate of a previous synthesis of the tetracyclic diterpene diol stemarin, 1, based on the application of the Wiesner photochemical method to the 8(9)-podocarpen-14-one, 3, was verified by means of model compound studies and MM calculations.File in questo prodotto:
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