Electrochemistry along with the microbial and photochemical approaches is a well established method for the degradation of wastes. It has been frequently stressed, however, that these methods often cannot bring about complete mineralization of several compounds, and to this end various methods broadly classified as AOPs (Advanced Oxidation Processes) provide complementary and alternative means of environment remediation, as outlined in comprehensive recent surveys. These AO systems include ozone, hydrogen peroxide as well as a mixture of them called "Peroxone" which can be activated by Fenton reactions leading to formation of a large amount of OH radicals and, consequently, to a highly oxidizing environment. In this work we investigate incineration of some phenolic compounds (4-chlorophenol, 4-nitrophenol, 2,4-dichlorophenoxyacetic acid, trans-3,4-dihydroxycinnamic acid) and methyl tert-butyl ether (MTBE) using different electrochemical systems involving ozone formation at PbO2 based anodes: (1) direct electrolysis at constant current; (2) ex-situ use of O-3 and (3) combined use of anodically generated O-3 and H2O2 produced at a graphite cathode. According to the results described in this work, what we called direct electrolysis actually turns out to be a mediated process by oxygenated radical intermediates. Subsequently, the active oxygen intermediates can react with the organic pollutants. The homogeneous chemical decomposition by ozone is the basis of the ex-situ methods. It involves the direct reaction of O-3 with the organic substrate and/or a radical chain reaction initiated by radicals formed in the reaction of O-3 with OH- or with HO2-. The latter pathway is favoured by an increase of the pH. The examination of the results shows that the combined use of anodically generated O-3 and H2O2 produced at cathode is the most efficient approach.
Electrochemical Incineration of Some Phenolic Compounds and MTBE
Amadelli R
2012
Abstract
Electrochemistry along with the microbial and photochemical approaches is a well established method for the degradation of wastes. It has been frequently stressed, however, that these methods often cannot bring about complete mineralization of several compounds, and to this end various methods broadly classified as AOPs (Advanced Oxidation Processes) provide complementary and alternative means of environment remediation, as outlined in comprehensive recent surveys. These AO systems include ozone, hydrogen peroxide as well as a mixture of them called "Peroxone" which can be activated by Fenton reactions leading to formation of a large amount of OH radicals and, consequently, to a highly oxidizing environment. In this work we investigate incineration of some phenolic compounds (4-chlorophenol, 4-nitrophenol, 2,4-dichlorophenoxyacetic acid, trans-3,4-dihydroxycinnamic acid) and methyl tert-butyl ether (MTBE) using different electrochemical systems involving ozone formation at PbO2 based anodes: (1) direct electrolysis at constant current; (2) ex-situ use of O-3 and (3) combined use of anodically generated O-3 and H2O2 produced at a graphite cathode. According to the results described in this work, what we called direct electrolysis actually turns out to be a mediated process by oxygenated radical intermediates. Subsequently, the active oxygen intermediates can react with the organic pollutants. The homogeneous chemical decomposition by ozone is the basis of the ex-situ methods. It involves the direct reaction of O-3 with the organic substrate and/or a radical chain reaction initiated by radicals formed in the reaction of O-3 with OH- or with HO2-. The latter pathway is favoured by an increase of the pH. The examination of the results shows that the combined use of anodically generated O-3 and H2O2 produced at cathode is the most efficient approach.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
