Proton Nuclear Magnetic Resonance (NMR) relaxation measurements have been performed down to very low temperature (50 mK) to determine the effect of coupling two Cr7Ni molecular rings via a Cu2+ ion. No difference in the spin dynamics was found from nuclear spin lattice relaxation down to 1.5 K. At lower temperature, the H-1-NMR line broadens dramatically indicating spin freezing. From the plot of the line width vs. magnetization, it is found that the freezing temperature is higher (260 mK) in the coupled ring with respect to the single Cr7Ni ring (140 mK). (C) 2014 AIP Publishing LLC.
Low temperature spin dynamics in Cr7Ni-Cu-Cr7Ni coupled molecular rings
Lascialfari A;
2014
Abstract
Proton Nuclear Magnetic Resonance (NMR) relaxation measurements have been performed down to very low temperature (50 mK) to determine the effect of coupling two Cr7Ni molecular rings via a Cu2+ ion. No difference in the spin dynamics was found from nuclear spin lattice relaxation down to 1.5 K. At lower temperature, the H-1-NMR line broadens dramatically indicating spin freezing. From the plot of the line width vs. magnetization, it is found that the freezing temperature is higher (260 mK) in the coupled ring with respect to the single Cr7Ni ring (140 mK). (C) 2014 AIP Publishing LLC.File in questo prodotto:
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