On the basis of first-principles calculations, we design a novel Cr-based metal-organic framework to be both multiferroic and magnetoelectric. The compound shows a "double-hybrid" nature: it is a hybrid organic-inorganic compound and it shows hybrid improper ferroelectricity. Here, the coupling of non-polar distortions, such as Jahn-Teller pseudo-rotations and tilting, pave the way to a polar behavior, with the coupling being realized through hydrogen bonds. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Hybrid improper ferroelectricity in a multiferroic and magnetoelectric metal-organic framework
Stroppa;Barone;Pa;Picozzi;Sa
2013
Abstract
On the basis of first-principles calculations, we design a novel Cr-based metal-organic framework to be both multiferroic and magnetoelectric. The compound shows a "double-hybrid" nature: it is a hybrid organic-inorganic compound and it shows hybrid improper ferroelectricity. Here, the coupling of non-polar distortions, such as Jahn-Teller pseudo-rotations and tilting, pave the way to a polar behavior, with the coupling being realized through hydrogen bonds. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.File in questo prodotto:
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