The crystal data of a number of carbonyl compounds have been reinvestigated. Interactions between carbonyl groups and pi-arene systems have been more deeply discussed from a stereochemical point of view revealing the presence of stabilizing interactions. Preliminar ab initio calculations are in agreement with this interpretation. (C) 1999 Elsevier Science S.A. All rights reserved.
Experimental evidence at atomic resolution of intra- and intermolecular CO center dot center dot center dot pi(arene) bond interactions
Manoli F;Venzo A
1999
Abstract
The crystal data of a number of carbonyl compounds have been reinvestigated. Interactions between carbonyl groups and pi-arene systems have been more deeply discussed from a stereochemical point of view revealing the presence of stabilizing interactions. Preliminar ab initio calculations are in agreement with this interpretation. (C) 1999 Elsevier Science S.A. All rights reserved.File in questo prodotto:
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Descrizione: Experimental evidence at atomic resolution of intra- and intermolecular CO center dot center dot center dot pi(arene) bond interactions
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