Organically modified silicas doped with TEMPO prepared via the sol-gel method are highly recyclable catalysts of the selective Montanari-Anelli oxidation of 1-nonanol; They show a notable "positive feedback" effect of matrix alkylation on the catalyst activity which is typical of doped sol-gel materials and markedly differentiates the behaviour of these materials from that of analogous silica-supported TEMPO.
Sol-gel Ormosils doped with TEMPO as Recyclable Catalysts for the Selective Oxidation of Alcohols
Rosaria Ciriminna;Mario Pagliaro
2002
Abstract
Organically modified silicas doped with TEMPO prepared via the sol-gel method are highly recyclable catalysts of the selective Montanari-Anelli oxidation of 1-nonanol; They show a notable "positive feedback" effect of matrix alkylation on the catalyst activity which is typical of doped sol-gel materials and markedly differentiates the behaviour of these materials from that of analogous silica-supported TEMPO.File in questo prodotto:
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