This article focuses on the progress obtained in the design of metal complexes which find application as sensitizers for dye-sensitized solar cells, DSSCs, and as electron shuttles in substitution of the triiodide/iodide redox couple. Coupling of sterically hindered dyes with mobile shuttles, based on a transition metal complex, represents the most advanced innovation which has allowed to reach on a single device the record efficiency of 12%. Issues which require further research are also discussed. (C) 2012 Elsevier B.V. All rights reserved.

The role of transition metal complexes in dye sensitized solar devices

Argazzi R;
2013

Abstract

This article focuses on the progress obtained in the design of metal complexes which find application as sensitizers for dye-sensitized solar cells, DSSCs, and as electron shuttles in substitution of the triiodide/iodide redox couple. Coupling of sterically hindered dyes with mobile shuttles, based on a transition metal complex, represents the most advanced innovation which has allowed to reach on a single device the record efficiency of 12%. Issues which require further research are also discussed. (C) 2012 Elsevier B.V. All rights reserved.
2013
Istituto per la Sintesi Organica e la Fotoreattivita' - ISOF
DSSC
Dye sensitizers
Electron transfer mediators
NANOCRYSTALLINE TIO2 FILMS
AMPHIPHILIC RUTHENIUM SENSITIZERS
ELECTRON-TRANSFER MEDIATORS
NEAR-IR SENSITIZATION
HIGHLY EFFICIENT
ORGANIC-DYES
CONVERSION-EFFICIENCY
CHARGE RECOMBINATION
PHOTOELECTROCHEMICAL PROPERTIES
POLYPYRIDINE COMPLEXES
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/20.500.14243/265158
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