The preparation and physical characterization of diverse porphyrin-derived double-walled carbon nanotubes (DWCNTs) conjugates are described. A porphyrin molecule is covalently linked and physically adsorbed to COOH-derived DWCNTs. The photophysical properties of all porphyrin-CNTs derivatives are studied in solution and in polymeric matrices. Definitive experimental evidence for photoinduced electron and/or energy transfer processes involving the porphyrin chromophores and the CNT wall is not obtained, but solid-state UV-vis absorption profiles display electronic transitions fingerprinting J- and H- type aggregates, where porphyrin molecules intermolecularly interact head-to-tail and face-to-face, respectively. In parallel, molecular modeling based on force-field simulations is performed to understand the structure of the porphyrin-CNTs interface and the nature of the interactions between the porphyrins and the DWCNTs. Finally, multilayered-type devices are fabricated with the aim of investigating the interaction of the porphyrin-derived DWCNTs with poly(3-hexylthiophene)-pyrene matrices containing small amounts of 1-[3-(methoxycarbonyl)propyl]-1-phenyl-[6.6]C61.
CNTs in Optoelectronic Devices: New Structural and Photophysical Insights on Porphyrin-DWCNTs Hybrid Materials
Armaroli;Nicola;
2012
Abstract
The preparation and physical characterization of diverse porphyrin-derived double-walled carbon nanotubes (DWCNTs) conjugates are described. A porphyrin molecule is covalently linked and physically adsorbed to COOH-derived DWCNTs. The photophysical properties of all porphyrin-CNTs derivatives are studied in solution and in polymeric matrices. Definitive experimental evidence for photoinduced electron and/or energy transfer processes involving the porphyrin chromophores and the CNT wall is not obtained, but solid-state UV-vis absorption profiles display electronic transitions fingerprinting J- and H- type aggregates, where porphyrin molecules intermolecularly interact head-to-tail and face-to-face, respectively. In parallel, molecular modeling based on force-field simulations is performed to understand the structure of the porphyrin-CNTs interface and the nature of the interactions between the porphyrins and the DWCNTs. Finally, multilayered-type devices are fabricated with the aim of investigating the interaction of the porphyrin-derived DWCNTs with poly(3-hexylthiophene)-pyrene matrices containing small amounts of 1-[3-(methoxycarbonyl)propyl]-1-phenyl-[6.6]C61.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
