Descrizione contenuto: Model tricyclic system I incorporating the complete array of oxygenated functions of the AB portion of forskolin was synthesized. The highly substituted decalin unit of the natural target was in turn assembled in a convenient way utilizing an intramol. nitrile oxide cycloaddn. reaction as key step. The structures of intermediates II-IV were detd. from x-ray data.
Synthetic studies towards Forskolin
POLO E;
1989
Abstract
Descrizione contenuto: Model tricyclic system I incorporating the complete array of oxygenated functions of the AB portion of forskolin was synthesized. The highly substituted decalin unit of the natural target was in turn assembled in a convenient way utilizing an intramol. nitrile oxide cycloaddn. reaction as key step. The structures of intermediates II-IV were detd. from x-ray data.File in questo prodotto:
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