An optically active Mn(III)-salen complex was supported on silica gel materials: the insoluble systems obtained were employed as catalysts in the asymmetric epoxidation of some aromatic olefins. Enantiomeric excess values up to 58% were obtained. (C) 1999 Elsevier Science Ltd. All rights reserved.
First example of a silica gel-supported optically active Mn(III)-salen complex as a heterogeneous asymmetric catalyst in the epoxidation of olefins
Orlandi S;
1999
Abstract
An optically active Mn(III)-salen complex was supported on silica gel materials: the insoluble systems obtained were employed as catalysts in the asymmetric epoxidation of some aromatic olefins. Enantiomeric excess values up to 58% were obtained. (C) 1999 Elsevier Science Ltd. All rights reserved.File in questo prodotto:
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Descrizione: First example of a silica gel-supported optically active Mn(III)-salen complex as a heterogeneous asymmetric catalyst in the epoxidation of olefins
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