A very simple experimental procedure at room temperature allowed to obtain optically active propargyl amines in very good yields and enantioselectivity up to 75%. The extremely simple methodology and the mild reaction conditions, as well as the possibility of a modular approach for developing new and more efficient bis-imine-based chiral ligands make the present methodology very attractive. (c) 2006 Elsevier B.V All rights reserved.
Asymmetric multicomponent copper catalyzed synthesis of chiral propargylamines
Orlandi Simonetta;
2006
Abstract
A very simple experimental procedure at room temperature allowed to obtain optically active propargyl amines in very good yields and enantioselectivity up to 75%. The extremely simple methodology and the mild reaction conditions, as well as the possibility of a modular approach for developing new and more efficient bis-imine-based chiral ligands make the present methodology very attractive. (c) 2006 Elsevier B.V All rights reserved.File in questo prodotto:
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Descrizione: Asymmetric multicomponent copper catalyzed synthesis of chiral propargylamines
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